鲜云南松露的挥发性香成分分析

采用顶空固相微萃取(SPME)法和同时蒸馏萃取(SDE)法提取鲜云南松露中的挥发性风味成分,利用气相色谱-质谱联用技术对挥发性风味成分进行分离鉴定。结果表明,经过GC-MS分析,共鉴定出77种挥发性成分,包括烃类5种、醛类14种、酮类12种、酸类4种、酯类2种、醇酚类10种、醚类2种、含硫含氮及其他杂环化合物28种。其中醛类、醇酚类和含硫含氮及其他杂环化合物对松露的特殊风味有着重要的影响。     

Synthesis,Corrosion Inhibition Performance and Biodegradability of Novel Alkyl Hydroxyethyl Imidazoline Salts

New alkyl hydroxyethyl imidazoline salts were synthesized via a high pressure process with imidazoline and dimethyl carbonate, and their chemical structure were confirmed using mass spectral fragmentation and FTIR spectroscopic analysis. In addition, several quaternary ammonium salts with new counterions (formic acid, acetic acid and lactic acid) were also synthesized by ion exchange reaction of methyl carbonate quaternary ammoniums with the corresponding acids. These new compounds reduced the surface tension of water to a minimum value of approximately 27 mN m^?1 at a concentration of 8.72 × 10^?5 mol L^?1. They also show efficient corrosion inhibition performances and could significantly inhibit the corrosion of mild steel in acid solutions. It was also found that the biological degradation of these imidazoline surfactants was greater than 98 % after 7 days.     

Model of interval multi-attribute optimization for overseas oil–gas projects

Because of the incompleteness and uncertainty in the information on overseas oil-gas projects,project evaluation needs models able to deal with such problems.A new model is,therefore,presented in this paper based on interval multi-attribute decision-making theory.Analysis was made on the important attributes(index) and the relationships affecting the basic factors to the project economic results were described.The interval numbers are used to describe the information on overseas oil and gas projects.On these bases,an improved TOPSIS model is introduced for the evaluation and ranking of overseas oil and gas projects.The practical application of the new model was carried out for an oil company in selecting some promising blocks from 13 oil and gas blocks in eight different countries in the Middle East.Based on these innovative studies,some conclusions are given from theoretical and application aspects.The practical application shows that the introduction of interval numbers into the evaluation and ranking of the overseas oil and gas projects can lead to more reasonable decisions.The users can do the project evaluation based on the comprehensive values as well as based on some preferred index in the project evaluation and ranking.     

A reliable and sensitive time-resolved fluorescent immunochromatographic assay (TRFICA) for ochratoxin A in agro-products

Immunochromatographic assays (ICAs) are considered as a suitable diagnostic tool for the detection of mycotoxins. Mycotoxins and especially, ochratoxin A are analytes with more demanding sensitivity requirements. To enhance the sensitivity of current immunochromatographic assays for ochratoxin A (OTA), a novel sensitive ICA was developed in this study. In the assay, microspheres enclosing fluorescent europium (III) [Eu(III)] nanoparticles (EuNPs) were used as a label for OTA monoclonal antibody (OTA-mAb) conjugation. Accordingly, assay was called time-resolved fluorescent immunochromatographic assay (TRFICA). The test strip was composed of three parts: a sample pad, nitrocellulose membrane and an absorbent pad. As for detection, a proper concentration of conjugated microspheres was pipetted into the microtube and sample extract was added to it. Then the strip was inserted into the tube and the fluid flow along the strip. The TRFICA results were obtained in 8 min and read by a portable TRFICA strip reader. The established method allows quantitative determination of OTA with limit of detection as low as 1.0 μg kg⁻¹ in the samples. For validation, spiked samples including wheat, maize, soybean and rice were respectively assayed by TRFICA and a standard high performance liquid chromatography equipped with a fluorescence detector (HPLC-FLD), and good agreement of results was obtained between two methods.     

Ex-ante evaluation of EU ETS during 2013–2030: EU-internal abatement

This study investigates CO₂ emission reduction within the EU resulting from the Emissions Trading Scheme (ETS) up to 2030. This is performed by constructing a baseline scenario without the ETS and assessing the impacts of the ETS, as currently designed. The results indicate that the ETS will start to impact emissions primarily after 2025 due to the prevalence of a sizable allowance surplus. The impact of approved (i.e. back-loading and 2.2% linear reduction factor (LRF)) and proposed (i.e. market stability reserve (MSR)) policy interventions and the inclusion of aviation, could accelerate the exhaustion of surplus and increase emission reductions during the investigated period. However, these measures would be insufficient to restore the scarcity of allowances and the corresponding carbon price before the start of ETS Phase IV, and the effectiveness of EU-internal abatement cannot be guaranteed until 2023. The effectiveness could be further reduced in the case of the economic shocks or the exclusion of international aviation.To restore the scarcity of allowances, other reform options are necessary. This paper extends the reasoning for the early removal of the back-loaded 900 Mtonne allowances by 2020 and broadening the scope of ETS to other sectors with potential high demand for allowances.     

一种针对类别数据分析的平行坐标改进方法

针对类别数据在传统平行坐标系中的映射重叠问题，提出类别统计和数据累积式偏移映射的平行坐标改进方法。该方法首先统计多维数据中的各类别数据的频次，使用直方图表示其记录数，将直方图与平行坐标相结合提出改进平行坐标。然后提出一种类别数据的数据累积式偏移算法，将映射在一点的数据均匀分布在坐标轴上的一定区域中，区域的范围根据数据记录数确定。最后设计实现可视化分析系统，通过改进平行坐标实现对数据集的筛选、条件交叉分析、类别间数据分析和维度间数据分析；通过联动视图和弦图两种方式实现每两个维度间的对比分析；通过字云显示每一维度的频次分布。案例数据集实验结果表明，该方法能在平行坐标中实现各维度中类别间的对比、各维度中记录数排序，以及对筛选数据集的分析，展示类别型数据维度间的关联关系。     

Strengthen flame retardancy of epoxy thermoset by montmorillonite particles adhering phosphorus-containing fragments

Phosphaphenanthrene derivative tri-(3-DOPO-2-hydroxypropan-1-yl)-1,3,5-triazine-2,4,6-trione (TGD) and organo-modified montmorillonite (OMMT) were jointly introduced into the diglycidyl ether of bisphenol A cured by 4,4-diamino-diphenylmethane (EP) to investigate their flame retardant behaviors. With only addition of 0.5%OMMT and 2.5%TGD, epoxy thermoset achieved a limiting oxygen index value of 33.7% and passed UL 94 V-0 rating test. Compared with the combustion behaviors of 3%OMMT/EP and 3%TGD/EP, an obvious synergistic flame retardant effect between OMMT and TGD can be concluded in OMMT/TGD/EP. Meanwhile, the FTIR spectra of gas-phase and condensed-phase products further proved this synergistic effect working in a physical way. On one hand, the co-existence of hydroxyl-containing TGD enabled montmorillonite (MMT) particles to filtrate and adhere more smoke fragments. On the other hand, the co-action of MMT help the polar phosphorus-containing fragments from TGD better strengthened char layer, enhancing the barrier and protective effect of residue. The synergistic flame retardant effect from OMMT/TGD system endowed themselves with higher flame retardant efficiency, and epoxy thermoset with better flame retardant performance. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 47500.     

The Digital Fingerprinting Analysis of Generic Twitter Sessions from Internet of Things Security Aspect

Nowadays, the unparalleled growth of Internet of Things (IoT) is a new digital disruption which intelligent devices are connected and working together. IoT connects personal computers, tablets, and smart phones in our daily communications from leisure purposes to business tasks. However, the security concern of IoT can’t be overemphasized due to the connectivity among communication gadgets. Sustainably, Twitter is one of the most popular Instant Message (IM) toolkits today. When Twitter is being utilized, there will be some negligible and imperceptible digital remnants left in the computing devices, which could be probative digital evidences in a court of law when IoT application is involved. Hence, the digital forensics of IM has been a relatively rigorous, competitive, and novel research field by the law enforcement agency officers and the information security staffs with respect to some cybercrimes concerning IoT. Consequently, this research is targeting on the utilization of Twitter on the desktop PC under Windows 7 operating system via the acquisition of volatile digital bread crumbs inside physical memory of the computing device for the purpose of presenting supportive digital evidences for some information security concerns. The proposed various scenarios in the design of the experiment could be the paradigms for digital forensics specialists or law enforcement agencies to follow in order to reconstruct the previous operations in the Twitter sessions of a certain user under the IoT ecosystems.

     

蛋白酶对排骨汤风味香精滋味的影响

为探究蛋白酶对热反应排骨汤风味香精滋味的影响，采用HPLC分析猪肉酶解液中游离氨基酸的含量，并结合感官评价和电子鼻分析技术对香精样品进行风味分析。得到制备排骨汤风味香精较优的蛋白酶复配条件为：m(木瓜蛋白酶):m(菠萝蛋白酶)=2:1，加酶量0.2%（酶质量占肉质量的百分数，下同）；优化后的酶解液中鲜味氨基酸总量最多，为26.70 g/L。利用电子鼻和感官评价指标进行主成分分析，能区分不同蛋白酶复配的香精。